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Superpositions of chiral states in the presence of electric dipole,magnetic dipole,and electric quadrupole interactions

机译:在存在电偶极子,磁偶极子和电四极子相互作用的情况下手性态的叠加

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摘要

This paper is a straightforward generalization of Maierle-Harris proposal regarding parity implications on the superpositions of chiral states of a molecule.It is shown that the inclusion of electric quadrupole and magnetic dipole interactions removes several of restrictions on the preparation of superpositions of |L> and |R> states of a chiral molecule.It is also found that the dephasing of |L> and |R> superpositions,due to the spontaneous emission from the chiral molecule,has opposing contributions from electric quadrupole-magnetic dipole and electric dipole interactions.
机译:本文是Maierle-Harris提议的简单概括,涉及奇偶性对分子手性态叠加的影响。研究表明,电四极和磁偶极相互作用的包含消除了对| L>叠加的制备的一些限制。还发现,由于手性分子的自发发射,| L>和| R>叠加的相移具有相反的电四极-磁偶极子和电偶极子相互作用的贡献。 。

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