Double-resonance spectroscopy of autoionizing states of ammonia

摘要

New double-resonance ionization data are presented on the autoionizing Rydberg states of NH3 excited via selected rotational levels of the (C) over tilde' (1)A(1)(0100) and (0200) states. Extrapolation of the Rydberg series provides a determination of the adiabatic ionization energy of NH3 that is in excellent agreement with that obtained by using zero kinetic energy photoelectron spectroscopy (ZEKE-PES). A comparison is presented between the field-free spectrum obtained by using a time-of-flight mass spectrometer and the 1-Tesla-spectrum obtained by using a magnetic-bottle electron spectrometer. Finally, the rotational and vibrational autoionization mechanisms are discussed. [S0021-9606(00)01006-0]. [References: 37]