A tethered aminohydroxylation route to L-arabino-[2R,3S,4R] and L-xylo-[2R,3S,4S]-C_(18)-phytosphingosines

Abhishek Dubey; Pradeep Kumar

首页> 外文期刊>Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry >A tethered aminohydroxylation route to L-arabino-[2R,3S,4R] and L-xylo-[2R,3S,4S]-C_(18)-phytosphingosines

【24h】

A tethered aminohydroxylation route to L-arabino-[2R,3S,4R] and L-xylo-[2R,3S,4S]-C_(18)-phytosphingosines

机译：L-阿拉伯糖-[2R，3S，4R]和L-木糖-[2R，3S，4S] -C_（18）-植物鞘氨醇的束缚氨基羟基化途径

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

A concise and highly efficient synthesis of L-arabino-[2R,3S,4R] and L-xylo-[2R,3S,4S]-C_(18)-phytosphingo-sines has been achieved. The synthetic strategy features the Sharpless kinetic resolution and tethered aminohydroxylation as the key steps.

机译：L-阿拉伯糖-[2R，3S，4R]和L-木糖-[2R，3S，4S] -C_（18）-植物鞘氨醇的简明高效合成方法已实现。合成策略以Sharpless动力学拆分和束缚的氨基羟基化为关键步骤。

著录项

来源
《Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry》 |2009年第26期|共3页
作者
Abhishek Dubey; Pradeep Kumar;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类
关键词
Sharpless asymmetric kinetic resolution; Tethered aminohydroxylation; Regioselectivity; Stereoselectivity; Phytosphingosine; Sphingolipids;

机译：锐利的不对称动力学拆分;束缚的氨基羟基化;区域选择性;立体选择性;植物鞘氨醇;鞘脂;

相似文献

外文文献
中文文献
专利

1. A tethered aminohydroxylation route to L-arabino-[2R,3S,4R] and L-xylo-[2R,3S,4S]-C_(18)-phytosphingosines [J] . Abhishek Dubey, Pradeep Kumar Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 2009,第26期

机译：L-阿拉伯糖-[2R，3S，4R]和L-木糖-[2R，3S，4S] -C_（18）-植物鞘氨醇的束缚氨基羟基化途径
2. Double stereodifferentiation in asymmetric dihydroxylation: application to the first diastereoselective synthesis of L-xylo-[2R,3S,4S]-C_18-phytosphingosine [J] . Rodney A.Fernandes, Pradeep Kumar Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 2000,第52期

机译：不对称二羟基化中的双立体分化：应用于L-木糖-[2R，3S，4S] -C_18-植物鞘氨醇的第一个非对映选择性合成
3. A Chemo-Enzymatic Expeditious Route to Racemic Dihexanoyl (2R*,3R*,4R*)-Dehydroxymethylepoxyquinomycin (DHMEQ), the Precursor for Lipase-Catalyzed Synthesis of the Potent Nuclear Factor-κB Inhibitor, (2S,3S,4S)-DHMEQ [J] . Chemical and Pharmaceutical Bulletin . 2012,第9期

机译：外消旋二己酰基（2R *，3R *，4R *）-脱羟基甲基环氧喹诺霉素（DHMEQ）的化学酶促快速路线，这是脂肪酶催化的有效核因子-κB抑制剂（2S，3S，4S）-DHMEQ的前体
4. A programmable computer chip-based, cruise-control system (C~3S) a cruise-control system with: automatic surge and spin reduction (AS~2R) features (C~3S/AS~2R) [C] . Avi Nelson, Dan Goor SAE International Congress and Exposition . 1999

机译：基于可编程计算机芯片的Cruise-Control系统（C〜3S）巡航控制系统，具有：自动浪涌和旋转减少（AS〜2R）特征（C〜3s / AS〜2R）
5. (3R,4S),(3S,4R) and (3R,4R),(3S,4S)-4-amino-5-fluoro-3-phenyl pentanoic acids as mechanism-based inactivators of 4-aminobutyric acid aminotransferase [D] . Nanavati, Shrenik M. 1988

机译：（3R，4S），（3S，4R）和（3R，4R），（3S，4S）-4-氨基-5-氟-3-苯基戊酸是基于机制的4-氨基丁酸氨基转移酶灭活剂
6. (2R,3S,4R)-3,4-Isopropylidenedioxy-2-(phenylsulfonylmethyl)pyrrolidin-1-ol [O] . Mari Fe Flores, Pilar Garcia, Narciso M. Garrido, 2015

机译：（2R，3S，4R）-3,4-异丙基二烯二氧基-2-（苯基磺酰基甲基基）吡咯烷-1-醇
7. Effective, High-Yielding, and Stereospecific Total Synthesis of d-erythro-(2R, 3S)-Sphingosine from d-ribo-(2S, 3S, 4R)-Phytosphingosine [O] . -1

机译：来自D-核酰基（2S，3S，4R）-phytosphinsine的D-yrythro-（2R，3S）-Sphingosine的有效，高屈服和立体合成的总合成

A tethered aminohydroxylation route to L-arabino-[2R,3S,4R] and L-xylo-[2R,3S,4S]-C_(18)-phytosphingosines

摘要

著录项

相似文献

相关主题

期刊订阅