A simple and convenient method for the preparation of diborane from tetrabutylammonium borohydride and benzyl chloride for application in organic synthesis

Mariappan Periasamy; G.P.Muthukumaragopal; Nalluri Sanjeevakumar

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A simple and convenient method for the preparation of diborane from tetrabutylammonium borohydride and benzyl chloride for application in organic synthesis

机译：一种简单方便的方法，由四丁基硼氢化铵和苄基氯制备有机硼烷，用于有机合成

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Diborane is readily generated in situ at 25 ~(deg)C in toluene using the Bu4NBH4/PhCH2Cl and Bu4NBH4/I2 reagent systems.The reagent prepared in this way is used for the reduction of carbonyl compounds and hydroboration-oxidation of olefins to obtain the corresponding alcohols in good yields.

机译：使用Bu4NBH4 / PhCH2Cl和Bu4NBH4 / I2试剂体系，乙硼烷很容易在25°C的甲苯中原位生成。以此方式制备的试剂用于还原羰基化合物和烯烃的氢硼化-氧化反应获得相应的醇，收率很高。

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《Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry》 |2007年第39期|共4页
作者
Mariappan Periasamy; G.P.Muthukumaragopal; Nalluri Sanjeevakumar;
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Tetrabutylammonium borohydride; Reduction; Hydro-boration; Oxidation.;

机译：四丁基硼氢化铵;还原;氢化硼化;氧化;

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1. A simple and convenient method for the preparation of diborane from tetrabutylammonium borohydride and benzyl chloride for application in organic synthesis [J] . Mariappan Periasamy, G.P.Muthukumaragopal, Nalluri Sanjeevakumar Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 2007,第39期

机译：一种简单方便的方法，由四丁基硼氢化铵和苄基氯制备有机硼烷，用于有机合成
2. Tetrabutylammonium peroxydisulfate in organic synthesis; IX: A convenient approach to the synthesis of fused acetal derivatives by tetrabutylammonium peroxydisulfate-mediated oxidative cycloaddition of 1,3-dicarbonyl compounds to cyclic enol ethers [J] . Chen FE., Meng G., Cheng Y., Synthesis: International Journal of Methods in Synthetic Organic Chemistry . 2000,第8期

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4. Synthesis of Sodium Borohydride from the Disproportionation of Diborane [C] . Wu Ying, Ortega Jeffrey V., Kelly Michael T. Towards a greener world . 2003

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机译：I.乙烯基烷氧基丙烯烯的氧化引发的纳扎罗夫环化。二。努力进行适于模拟合成的罗卡酰胺的合成。三，合成多取代苯酚衍生物的便捷环芳构化方法：方法开发和机理研究
6. A simple and convenient one-pot synthesis of substituted isoindolin-1-ones via lithiation substitution and cyclization of N-benzyl-NN-dimethylureas [O] . Keith Smith, Gamal A El-Hiti, Amany S Hegazy, 2011

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8. Convenient Synthesis of Solvated and Unsolvated Anhydrous Metal Chlorides viaDehydration of Metal Chloride Hydrates with Trimethylchlorosilane [R] . So, J. H., Boudjouk, P. 1990

机译：用三甲基氯硅烷脱水合成金属氯化物水合物方便合成溶剂化和非溶剂化无水金属氯化物

A simple and convenient method for the preparation of diborane from tetrabutylammonium borohydride and benzyl chloride for application in organic synthesis

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