Highly selective synthesis of 1-(silyl)-1-(boryl)ethenes via a ruthenium-catalyzed silylative coupling reaction

Magdalena Jankowska; Bogdan Marciniec; Cezary Pietraszuk; Joanna Cytarska; Marek Zaidlewicz

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Highly selective synthesis of 1-(silyl)-1-(boryl)ethenes via a ruthenium-catalyzed silylative coupling reaction

机译：通过钌催化的甲硅烷基化偶联反应高选择性地合成1-（甲硅烷基）-1-（硼基）乙烯

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An efficient silylative coupling of trisubstituted vinylsilanes with dialkoxy(vinyl)boranes is described.Under optimum conditions the reaction offers a selective route to l-(silyl)-l-(boryl)ethenes,which are potentially attractive intermediates in organic-synthesis.

机译：描述了三取代乙烯基硅烷与二烷氧基（乙烯基）硼烷的有效甲硅烷基化偶联。在最佳条件下，反应提供了选择路线以生成1-（甲硅烷基）-1-（硼基）乙烯，这是有机合成中潜在的有吸引力的中间体。

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《Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry》 |2004年第35期|共4页
作者
Magdalena Jankowska; Bogdan Marciniec; Cezary Pietraszuk; Joanna Cytarska; Marek Zaidlewicz;
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正文语种 eng
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silylative coupling; vinylsilanes; vinylboranes; ruthenium;

机译：硅烷化偶联;乙烯基硅烷;乙烯基硼烷;钌;

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1. Highly selective synthesis of 1-(silyl)-1-(boryl)ethenes via a ruthenium-catalyzed silylative coupling reaction [J] . Magdalena Jankowska, Bogdan Marciniec, Cezary Pietraszuk, Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 2004,第35期

机译：通过钌催化的甲硅烷基化偶联反应高选择性地合成1-（甲硅烷基）-1-（硼基）乙烯
2. Gold(I)-Catalyzed Reactions of 1-(prtho-Alkynylaryl)ureas: Highly Selective Heterocyclization and Synthesis of Mixed N,O-Acetals [J] . Ana Gimeno, Ana B. Cuenca, Mercedes Medio-Simon Advanced synthesis & catalysis . 2014,第1期

机译：金（I）催化的1-（邻炔烷基芳基）脲的反应：高度选择性的杂环化和混合N，O-缩醛的合成
3. Radical addition reactions of fluorinated species.part 7.Highly selective two-step synthesis of 1-(polyfluoroalkyl)ethane-1,2-diols;regioselectivety of the additions of methylated 1,3-dioxolanes to perfluoroolefins [J] . Cirkva Vladimir, Paleta Oldrich Journal of Fluorine Chemistry . 1999,第Juna期

机译：氟化物种的自由基加成反应。第7部分：1-（聚氟烷基）乙烷-1,2-二醇的高选择性两步合成;甲基化1,3-二氧戊环向全氟烯烃的加成区域选择性
4. Synthesis and Photochromic Properties of 1-(Thien-3-yl)-2-(thien-2-yl)- ethene Having Bromo at 4-Position of Thiophene Moieties [C] . Shengmin Zhao, Rui Zhao, Xian Chen, International Conference on Chemical Engineering and Advanced Materials . 2012

机译：1-（噻吩-3-基）-2-（噻吩-2-基） - 乙烯的合成和光致变色性质在噻吩部分的4-位具有Bromo
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机译：I.1-（2-蒽基）-2-环丙基乙烯和1-（2-萘基）-2-环丙基乙烯的合成，分离和表征。二。卤代醚的二氧化钛光催化：机理研究。
6. Friedel–Crafts-type reaction of pyrene with diethyl 1-(isothiocyanato)alkylphosphonates. Efficient synthesis of highly fluorescent diethyl 1-(pyrene-1-carboxamido)alkylphosphonates and 1-(pyrene-1-carboxamido)methylphosphonic acid [O] . Anna Wrona-Piotrowicz, Janusz Zakrzewski, Anna Gajda, 2015

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7. A New Selective Approach to 1, 1-Bis(silyl)-2-arylethenes and 1, 1-Bis(silyl)-1, 3-butadienes via Sequential Silylative Coupling-Heck Coupling Reactions [O] . -1

机译：通过顺序甲硅烷基偶联 - Heck偶联反应，通过顺序甲硅烷基偶联 - Heck偶联反应进行新的选择性方法1,1-双（甲硅烷基）-2-淀粉和1,1和双（甲硅烷基）-1,3-丁二烯
8. Branching Ratios and Rate Constants for Reactions of (16)O(1-) and (18)O(1-) withN2O and (14)N(15)N(16)O [R] . Morris, R. A., Viggiano, A. A., Paulson, J. F. 1990

机译：（16）O（1-）和（18）O（1-）与N2O和（14）N（15）N（16）O反应的支化比和速率常数

Highly selective synthesis of 1-(silyl)-1-(boryl)ethenes via a ruthenium-catalyzed silylative coupling reaction

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