Sulfamic acid as cost-effective and recyclable catalyst for liquid Beckmnn rearrangement,a green process to produce amides from ketoximes without waste.

摘要

Sulfamic aicd (H_2NSO_3H)has been proed to be an efficient and green catalyst for liquid Beckmann rearrangement of ketoxime in dried acetonitrile.The use of basic neutralization agent has been avoided in this system due ot its intrinsic zwitterionic property.thus it is a green process for preparation of amide from ketoxime without producing any waste.