The synthesis of baclofen and GABOB via Rh(II) catalyzed intramolecular C-H insertion of alpha-diazoacetamides

Chen ZL; Chen ZY; Jiang YZ; Hu WH

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The synthesis of baclofen and GABOB via Rh(II) catalyzed intramolecular C-H insertion of alpha-diazoacetamides

机译：Rh（II）催化α-重氮乙酰胺的分子内C-H插入合成巴氯芬和GABOB

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The synthesis of baclofen and GABOB is reported via hydrolysis of the corresponding X-ten-butyl gamma-lactams. which were obtained from Rh(II) catalyzed intramolecular C-H insertion of alpha-diazoacetamides. (C) 2004 Elsevier Ltd. All rights reserved.

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《Tetrahedron》 |2005年第6期|共8页
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Chen ZL; Chen ZY; Jiang YZ; Hu WH;
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C-H insertion; gamma-lactam; gabapentin; baclofen; GABA; CARBON-HYDROGEN INSERTION; (-)-GAMMA-AMINO-BETA-HYDROXYBUTYRIC ACID GABOB; ENANTIOSELECTIVE SYNTHESIS; STEREOSELECTIVE-SYNTHESIS; ANTICONVULSANT AGENTS; MICHAEL ADDITION; GLUTAMIC ACID; GAMMA-LACTAM; (R)-(-)-BACLOFEN; DIRHODIUM(II);

机译：CH插入;γ-内酰胺;加巴喷丁;巴洛芬;GABA;碳-氢插入;（-）-γ-氨基-BETA-羟基丁酸GABOB;对映体选择性合成;立体选择性合成;对映体助剂;MMA助剂内酰胺;（R）-（-）-巴氯芬;二铑（II）;

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1. The synthesis of baclofen and GABOB via Rh(II) catalyzed intramolecular C-H insertion of alpha-diazoacetamides [J] . Chen ZL, Chen ZY, Jiang YZ, Tetrahedron . 2005,第6期

机译：Rh（II）催化α-重氮乙酰胺的分子内C-H插入合成巴氯芬和GABOB
2. Ruthenium-Catalyzed Stereoselective Intramolecular Carbenoid C-H Insertion for beta-and gamma-Lactam Formations by Decomposition of alpha-Diazoacetamides [J] . Matthew Kwok-Wai Choi, Wing-Yiu Yu, Chi-Ming Che Organic letters . 2005,第6期

机译：钌催化的α-重氮乙酰胺分解的β-和γ-内酰胺形成的立体选择性分子内类胡萝卜素C-H插入
3. Dirhodium-catalyzed enantioselective C-H insertion of N-(2-benzyloxyethyl)-N-(tert-butyl) diazoacetamide and its application for the synthesis of chiral GABOB [J] . Du ZJ, Chen ZL, Chen ZY, Chirality: The pharmacological, biological, and chemical consequences of molecular asymmetry . 2004,第8期

机译：N-（2-苄氧基乙基）-N-（叔丁基）重氮乙酰胺的吡啶催化对映选择性C-H插入及其在手性GABOB合成中的应用
4. Highly Chemo- and Stereoselective Asymmetric Intramolecular C-H Insertion Reaction Catalyzed by Ru(II)-Pheox Complex [C] . Nga Phan Thi Thanh, Soda Chanthamath, Kazutaka Shibatomi 日本化学会春季年会講演予稿集 . 2018

机译：高效和立体选择性的不对称分子内的C-H插入反应催化Ru（II） - 苯甲络合物
5. Part I: An approach to the synthesis of plakortethers A--E; Part II: Rhodium-catalyzed intramolecular C--H insertion on diazosulfonates and its synthetic applications. [D] . Liyanage, Duminda Shiromalee. 2014

机译：第一部分：合成普拉克醚醚A--E的方法；第二部分：重氮磺酸盐上铑催化的分子内C–H插入及其合成应用。
6. Asymmetric intramolecular C-H insertion of sulfonyldiazoacetates catalyzed by Rh(II) [O] . Christian S. Jungong, Alexei V. Novikov -1

机译：通过铑催化的sulfonyldiazoacetates的不对称分子内C-H插入（II）
7. Rhodium(II)-catalyzed intramolecular C-H insertion α- to oxygen: reactivity, selectivity and applications to natural product synthesis [O] . Lombard Fanny, Coster Mark 2015

机译：铑（II）催化的分子内C-H插入氧中-反应性，选择性及其在天然产物合成中的应用

The synthesis of baclofen and GABOB via Rh(II) catalyzed intramolecular C-H insertion of alpha-diazoacetamides

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