A convergent total synthesis of epolactaene: an application of the bridgehead oxiranyl anion strategy

Kuramochi K.; Nagata S.; Itaya H.; Matsubara Y.; Sunoki T.; Uchiro H. Takao K.; Kobayashi S.

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A convergent total synthesis of epolactaene: an application of the bridgehead oxiranyl anion strategy

机译：收敛的全合成大环内烯：桥头环氧乙烷基阴离子策略的应用

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摘要

The generation and reaction of a lactone-derived oxiranyl anion is described. The aldol-type reaction of the epoxylactone and aldehydes was accomplished by a two-step procedure via the trimethylsilyl epoxylactone. The application of this methodology to the total synthesis of (+)-epolactaene and its analogs is described. (C) 2003 Elsevier Ltd. All rights reserved. [References: 52]

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《Tetrahedron》 |2003年第49期|共16页
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Kuramochi K.; Nagata S.; Itaya H.; Matsubara Y.; Sunoki T.; Uchiro H. Takao K.; Kobayashi S.;
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Epolactaene; Epoxylactone; Tbaf; Aldol reaction; Human neuroblastoma-cells; Asymmetric total synthesis; Alpha-heterosubstituted epoxides; Z-unsaturated esters; Neuritogenic compound; Selective oxidation; Practical synthesis; Potent antagonist; M-2 subtype; Side-chain;

机译：依帕内烯;环氧内酯;Tbaf;Aldol反应;人类神经母细胞瘤细胞;不对称全合成;α-不饱和取代的环氧化物;Z-不饱和酯;产神经化合物;选择性氧化;实用合成;强拮抗剂;M-2亚型;侧链;
入库时间 2022-08-19 14:37:20

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1. 光系统Ⅱ颗粒内单线态氧诱导产生超氧阴离子自由基 [J] . 刘科, 孙健, 徐英凯, 植物学报（英文版） . 2001,第009期
2. A convergent total synthesis of epolactaene: an application of the bridgehead oxiranyl anion strategy [J] . Kuramochi K., Nagata S., Itaya H., Tetrahedron . 2003,第49期

机译：收敛的全合成大环内烯：桥头环氧乙烷基阴离子策略的应用
3. Divergent Synthesis of Trans-Fused Polycyclic Ethers by a Convergent Oxiranyl Anion Strategy [J] . Takeo Sakai, Ai Sugimoto, Hiroki Tatematsu, The Journal of Organic Chemistry . 2012,第24期

机译：收敛性环氧乙烷基阴离子策略发散合成反式多环醚
4. Divergent synthesis of trans-fused polycyclic ethers by a convergent oxiranyl anion strategy [J] . Sakai T., Sugimoto A., Tatematsu H., The Journal of Organic Chemistry . 2012,第24期

机译：收敛性氧杂环丁基阴离子策略发散合成反式稠合多环醚
5. Taming dinitramide anions within an energetic cationic metal-organic framework via simple anion exchange: a new strategy for synthesis and tunable properties of high energy materials [C] . Jichuan Zhang, Yao Du, Kai Dong, Seminar on New Trends in Research of Energetic Materials . 2016

机译：通过简单的阴离子交换，在高能阳离子金属-有机框架内驯化二硝酰胺阴离子：高能材料的合成和可调谐特性的新策略
6. Application of the type 2 intramolecular Diels-Alder reaction: 1. Synthesis and chemistry of bridgehead allylsilanes and 2. Synthetic efforts towards the total synthesis of welwitindolinones [D] . Lauchli, Ryan Mark 2007

机译：2型分子内Diels-Alder反应的应用：1.桥头烯丙基硅烷的合成和化学反应； 2.合成魏维多灵酮的全合成方法
7. Organometallic Enantiomeric Scaffolding. Sequential Semipinacol / 15-Michael-like Reactions as a Strategic Approach to Bridgehead-Quaternary Center Aza3.3.1Bicyclics: Application to the Total Synthesis of (-)-Adaline [O] . Thomas C. Coombs, Yongqiang Zhang, Ethel C. Garnier-Amblard, -1

机译：有机金属对映体支架。顺序Semipinacol / 15- Michael-like反应作为桥头四元中心氮杂3.3.1双环化合物的战略方法：在（-）-Adaline的总合成中的应用
8. Correction to “Formal Total Synthesis of Hemibrevetoxin B by an Oxiranyl Anion Strategy” [O] . Yuji Mori, Keisuke Yaegashi, Hiroshi Furukawa 2019

机译：校正“通过氧化氧基阴离子策略”的“正式总合成六纤维毒素”

A convergent total synthesis of epolactaene: an application of the bridgehead oxiranyl anion strategy

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