Local switching in epitaxial YHx switchable mirrors - art. no. 075417

摘要

All the essential switchable mirror properties of YHx exhibit a strong hysteresis that is related to the structural beta-dihydride to gamma-trihydride phase transition. This structural transition in YHx has so far been difficult to investigate since polycrystalline YHx films are optically homogeneous on the length scale of visible light wavelengths. However, in epitaxial YHx films the relation between local structural changes and local optical transmission can be investigated using in situ atomic force microscopy and optical microscopy, in hysteretic yttriumhydride mirrors exhibiting the earlier reported, domainwise pixel switching. We find widely varying local switching kinetics during the whole hydrogenation process. As a result, an epitaxial mirror forms essentially an ensemble of individual microcolumns, each of which can be in three regimes: (i) a single-phase regime of the beta dihydride phase, where the optical transmission lowers with increasing hydrogen concentration, (ii) a layered two phase configuration in which the optical transmission rises with the fraction of high-concentration gamma phase, and (iii) a single-gamma-phase regime in which the transmission still increases significantly. The effect of a wide distribution of local properties on the global mirror properties are discussed within a simple model. [References: 23]