Axial 4,4 ',6,6 '-Tetrakis-trifluoromethyl-biphenyl-2,2 '-diamine (TF-BIPHAM): Resolution and Applications in Asymmetric Hydrogenation

Wang CJ; Gao F; Liang G

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Axial 4,4 ',6,6 '-Tetrakis-trifluoromethyl-biphenyl-2,2 '-diamine (TF-BIPHAM): Resolution and Applications in Asymmetric Hydrogenation

机译：轴向4,4'，6,6'-四-三氟甲基-联苯-2,2'-二胺（TF-BIPHAM）：拆分和在不对称加氢中的应用

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摘要

The racemic TF-BIPHAM was resolved for the first time, and the effectiveness of the resolved diamine was demonstrated by highly enantioselective hydrogenation of alpha-aryl enamides and (x-dehydroamino acid esters using readily accessible bis(aminophosphine) ligands.

机译：外消旋的TF-BIPHAM首次被拆分，并且拆分后的二胺的有效性通过使用易于获得的双（氨基膦）配体对α-芳基酰胺和（x-脱氢氨基酸酯）进行高度对映选择性加氢来证明。

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《Organic letters》 |2008年第21期|共4页
作者
Wang CJ; Gao F; Liang G;
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正文语种 eng
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OPTICAL RESOLUTION; ENANTIOSELECTIVE HYDROGENATION; CHIRAL LIGANDS; COMPLEXATION; ACIDS; 2; 2'-DIHYDROXY-1; 1'-BINAPHTHYL; 2; 2'-DIAMINO-1; 1'-BINAPHTHYL; BISPHOSPHINE; BINAPHTHYL; CATALYSIS;

机译：光学分辨率;对映体选择性加氢;手性配体;络合物;酸;2;2'-二羟基-1;1'-联萘;2;2'-二氨基-1;1'-联萘;双磺胺;联萘;催化;

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1. Axial 4,4 ',6,6 '-Tetrakis-trifluoromethyl-biphenyl-2,2 '-diamine (TF-BIPHAM): Resolution and Applications in Asymmetric Hydrogenation [J] . Wang CJ, Gao F, Liang G Organic letters . 2008,第21期

机译：轴向4,4'，6,6'-四-三氟甲基-联苯-2,2'-二胺（TF-BIPHAM）：拆分和在不对称加氢中的应用
2. A Convenient Synthesis of 2,2',6,6'-Tetramethoxy-4,4'-bis(dicyclohexylphosphino)-3,3'-bipyridine(Cy-P-Phos):Application in Rh-Catalyzed Asymmetric Hydrogenation of alpha-(Acylamino)acrylates [J] . Jing Wu, Terry T.-L.Au-Yeung, Wai-Him Kwok, Advanced synthesis & catalysis . 2005,第4期

机译：2,2'，6,6'-四甲氧基-4,4'-双（二环己基膦基）-3,3'-联吡啶（Cy-P-Phos）的简便合成：在Rh-催化α-不对称加氢反应中的应用（酰基氨基）丙烯酸酯
3. Axially 4,4-di-tert-butyl TunePhos-type chiral diphosphine ligand: synthesis and applications in asymmetric hydrogenation [J] . Chun-Jiang Wang, Chu-Bei Wang, Dong Chen Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 2009,第9期

机译：轴向4,4-二叔丁基TunePhos型手性二膦配体：不对称氢化的合成及应用
4. Synthesis of Polymer-supported Chiral 1,2-Diamine by Polycondensation and Its Application to Asymmetric Hydrogenation [C] . Naoki Haraguchi, Nilesh Anand Prasad, Takao Uchiyama, World Multiconference on Systemics, Cybernetics and Informatics . 2006

机译：通过缩聚合成聚合物支持的手性1,2-二胺及其在不对称氢化中的应用
5. Catalytic Asymmetric Hydrogenation: Toward Chiral Diamines and Cyclohexanes. [D] . Pignatelli, Joseph. 2011

机译：催化不对称加氢：手性二胺和环己烷。
6. Designof Ru(II)-NHC-Diamine Precatalysts Directedby Ligand Cooperation: Applications and Mechanistic Investigationsfor Asymmetric Hydrogenation [O] . Wei Li, Tobias Wagener, Lars Hellmann, -1

机译：设计的Ru（II）-NHC-二胺预催化剂的制备配体合作公司：应用和机理研究用于不对称加氢
7. Atroposelective Transfer Hydrogenation of Biaryl Aminals via Dynamic Kinetic Resolution. Synthesis of Axially Chiral Diamines [O] . -1

机译：通过动态动力学分辨率，通过动态动力学分辨率转移芳基芳烃的AtropoSelective氢化。轴向手性二胺的合成
8. Aromatic Diamines and Polyimides Based on 4,4'-Bis-(4-Aminophenoxy)-2,2' or 2,2',6,6'- Substituted Biphenyl [R] . 2000

机译：基于4,4'-双 - （4-氨基苯氧基）-2,2'或2,2'，6,6'-取代联苯的芳香二胺和聚酰亚胺

Axial 4,4 ',6,6 '-Tetrakis-trifluoromethyl-biphenyl-2,2 '-diamine (TF-BIPHAM): Resolution and Applications in Asymmetric Hydrogenation

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