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Multiphoton near-infrared quantum cutting luminescence of Yb~(3+) ion cooperative energy transferred from the oxyfluoride vitroceramics phosphor matrix

机译:从氟氧化物玻璃陶瓷磷光体基质转移的Yb〜(3+)离子协同能的多光子近红外量子切割发光

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摘要

In this Letter, we reported on an interesting multiphoton infrared quantum cutting phenomenon in Yb~(3+)Tb~(3+)-doped oxyfluoride vitroceramics phosphors. From the study results it is found that the absorption of one 288.0 nm photon of the matrix results in the emission of two 975.5 nm photons of the Yb~(3+) ion. In addition, it is found also that one 255.0 nm photon of the matrix may result in the emission of three 975.5 nm photons of the Yb~(3+) ion, due to the fact that their cooperative energy transfer rate is larger than multiphonon nonradiative relaxation rate.
机译:在这封信中,我们报道了掺Yb〜(3+)Tb〜(3+)的氟氧化物玻璃陶瓷荧光粉中有趣的多光子红外量子切割现象。从研究结果中发现,基质的一个288.0 nm光子的吸收导致发射两个Yb〜(3+)离子975.5 nm光子。另外,还发现,由于它们的协同能量传递速率大于多声子非辐射性的事实,矩阵的一个255.0 nm光子可能导致发射三个975.5 nm光子的Yb〜(3+)离子。松弛率。

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