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Kinetics study of crystallization with the disorder-bcc-fcc phase transition of charged colloidal dispersions

机译:带电胶体分散体无序-bcc-fcc相变结晶的动力学研究

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摘要

Structure transformation (disorder-bcc-fcc) in charged colloidal dispersions, as a manifestation of the Ostwald's step rule, was confirmed by means of reflection spectrum (RS) measurements in our previous study. By taking advantage of a reflection spectrum containing plenty of information about the crystallization behaviors, time-dependent changes of parameters associated with the crystal structure and composition during the disorder-bcc-fcc transition are reported by treating the data from RS in this article. In addition, Avrami's model is adopted to analyze the transition process and investigate the transition rate. On the basis of the above investigations, associated kinetic features of crystallization with the disorder-bcc-fcc transition are described.
机译:通过以前的研究中的反射光谱(RS)测量,证实了带电胶体分散体中的结构转变(disorder-bcc-fcc),这是奥斯特瓦尔德阶跃规则的体现。通过利用包含大量有关结晶行为信息的反射光谱,通过处理本文中来自RS的数据,报告了无序-bcc-fcc转变过程中与晶体结构和组成相关的参数随时间的变化。此外,采用Avrami模型分析过渡过程并研究过渡速率。基于上述研究,描述了具有无序-bcc-fcc转变的结晶的相关动力学特征。

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