The experiment research of corrosion behaviour about Ni-based alloys in simulant solution containing H_2S/CO_2

摘要

Aimed at the problem of tubing corrosion in environment that containing hydrogen sulfide (H_2S), carbon dioxide (CO_2), and chlorides (Cl~-), the corrosion behaviour of two nickel based alloys (UNS 06985 and UNS 08825) in 15 wt%NaCl solution containing H_2S/CO_2 in high temperature and high pressure environment was investigated. The pitting corrosion behaviour of Ni-based alloys was studied in FeCl_3·6H_2O solution by means of polarisation curve and immersion tests. The scanning electron microscopy (SEM), energy disperse spectroscopy (EDS) was applied to analyse the microstructure and corrosion performance of the samples. The results showed that the pitting-resistant of nickel alloy UNS 06985 was superior to UNS 08825. With the rising of experimental temperature, the corrosion increased and some slight pitting attacks appeared on the surface of UNS 08825. The test temperature was the crucial factor that influenced not only the compactness and the growing rate of corrosion product scale, but also the corrosion rate of the alloys. Elemental sulfur is a strong oxidant, the presence of SO leads to a serious localized corrosion. XRD showed that the corrosion films formed on nickel base alloys consisted of NiS, CrO_3, and the oxides of Ni and Fe. The polarisation curves showed a different corrosion behaviour of two alloys, anodic curve of UNS 06985 has a wider passivation area, and there has higher transpassive potential.