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首页> 外文期刊>Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics >Diphenoxo-bridged Ni ~II Ln ~III dinuclear complexes as platforms for heterotrimetallic (Ln ~IIINi ~II) _2Ru ~III systems with a high-magnetic-moment ground state: Synthesis, structure, and magnetic properties
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Diphenoxo-bridged Ni ~II Ln ~III dinuclear complexes as platforms for heterotrimetallic (Ln ~IIINi ~II) _2Ru ~III systems with a high-magnetic-moment ground state: Synthesis, structure, and magnetic properties

机译:具有高磁矩基态的二苯氧基桥连的Ni〜II Ln〜III双核络合物作为杂三金属(Ln〜IIINi〜II)_2Ru〜III系统的平台:合成,结构和磁性

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摘要

The first examples of pentanuclear heterotrimetallic [(LnNi) _2Ru] [Ln ~(3+) = Gd (1) and Dy (2)] complexes were prepared and magnetostructurally characterized. They exhibit ferromagnetic interactions, leading to a high-magnetic-moment ground state.
机译:制备五核杂三金属[(LnNi)_2Ru] [Ln〜(3+)= Gd(1)和Dy(2)]配合物的第一个实例,并对其磁结构进行了表征。它们表现出铁磁相互作用,导致高磁矩基态。

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