Reversible addition of water to the high-hydride-content cluster [Rh-6((PPr3)-Pr-i)(6)H-12][BAr4F](2). Synthesis and structure of [Rh-6((PPr3)-Pr-i)(6)H-11(OH)][BAr4F](2)

Douglas TM; Brayshaw SK; Raithby PR; Weller AS

首页> 外文期刊>Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics >Reversible addition of water to the high-hydride-content cluster [Rh-6((PPr3)-Pr-i)(6)H-12][BAr4F](2). Synthesis and structure of [Rh-6((PPr3)-Pr-i)(6)H-11(OH)][BAr4F](2)

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Reversible addition of water to the high-hydride-content cluster [Rh-6((PPr3)-Pr-i)(6)H-12][BAr4F](2). Synthesis and structure of [Rh-6((PPr3)-Pr-i)(6)H-11(OH)][BAr4F](2)

机译：向高氢化物含量簇[Rh-6（（PPr3）-Pr-1）（6）H-12] [BAr4F]（2）中可逆添加水。 [Rh-6（（PPr3）-Pr-i）（6）H-11（OH）] [BAr4F]（2）的合成与结构

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The hydroxyhydrido salt [Rh-6((PPr3)-Pr-i)(6)H-11(OH)][BAr4F](2) results from the addition of water to [Rh-6((PPr3)-Pr-i)(6)H-12][BAr4F](2). This reaction is ;reversible, and the addition of dihydrogen to [Rh-6((PPr3)-Pr-i)(6)H-11(OH)]- [BAr4F](2) results in the elimination of water and the regeneration of the hydride cluster.

机译：羟基氢盐[Rh-6（（PPr3）-Pr-1）（6）H-11（OH）] [BAr4F]（2）是由于在[Rh-6（（PPr3）-Pr- i）（6）H-12] [BAr4F]（2）。该反应是可逆的，向[Rh-6（（PPr3）-Pr-i）（6）H-11（OH）]-[BAr4F]（2）中添加二氢可消除水和氢化物簇的再生。

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来源
《Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics》 |2008年第3期|共3页
作者
Douglas TM; Brayshaw SK; Raithby PR; Weller AS;
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正文语种 eng
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IR-I COMPLEXES; OXIDATIVE ADDITION; O-H; POLYHYDRIDO CLUSTERS; HYDROGEN STORAGE; BOND; ACTIVATION; RUTHENIUM; LIGANDS; REACTIVITY;

机译：IR-I络合物;氧化添加剂;O-H;聚羟基团簇;储氢;结合;活化;液体;反应;

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1. Reversible addition of water to the high-hydride-content cluster [Rh-6((PPr3)-Pr-i)(6)H-12][BAr4F](2). Synthesis and structure of [Rh-6((PPr3)-Pr-i)(6)H-11(OH)][BAr4F](2) [J] . Douglas TM, Brayshaw SK, Raithby PR, Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2008,第3期

机译：向高氢化物含量簇[Rh-6（（PPr3）-Pr-1）（6）H-12] [BAr4F]（2）中可逆添加水。 [Rh-6（（PPr3）-Pr-i）（6）H-11（OH）] [BAr4F]（2）的合成与结构
2. Synthesis and reactivity of novel ruthenium carbene catalysts. X-ray structures of [RuCl2(=CHSC6H5)((PPr3)-Pr-i)(2)] and [RuCl2(CHCH2CH2-C,N-2-C5H4N)((PPr3)-Pr-i)] [J] . van der Schaaf PA., Kirner HJ., Rime F., Journal of Organometallic Chemistry . 2000,第1期

机译：新型钌卡宾催化剂的合成与反应性。 [RuCl2（= CHSC6H5）（（PPr3）-Pr-i）（2）]和[RuCl2（CHCH2CH2-C，N-2-C5H4N）（（PPr3）-Pr-i）]的X射线结构
3. Synthesis and characterization of hydride-alkynyl, allenylidene, carbyne, and functionalized-alkynyl complexes containing the [Os(eta(5)-C5H5) ((PPr3)-Pr-i)(-)(2)](+) fragment: The complex [Os(eta(5)-C5H5)(C=C=CPh2)((PPr3)-Pr-i)(2)]PF6, a new type of [J] . Baya M., Esteruelas MA., Gutierrez-Puebla E., Organometallics . 2000,第13期

机译：包含[Os（eta（5）-C5H5）（（PPr3）-Pr-i）（-）（-）（2）]（+）片段的氢化物-炔基，亚烯基，碳炔和官能化的炔基配合物的合成和表征：复杂的[Os（eta（5）-C5H5）（C = C = CPh2）（（PPr3）-Pr-i）（2）] PF6
4. Using EPR to follow reversible dihydrogen addition to paramagnetic clusters of high hydride count: Rh-6(PCy3)(6)H-12(+) and Rh-6(PCy3)(6)H-14(+) [O] . Hiney Rachel M., Chaplin Adrian B., Harmer Jeffrey, 2010

机译：使用EPR追踪可逆的二氢加成至高氢化物数的顺磁性簇：Rh-6（PCy3）（6）H-12（+）和Rh-6（PCy3）（6）H-14（+）

Reversible addition of water to the high-hydride-content cluster [Rh-6((PPr3)-Pr-i)(6)H-12][BAr4F](2). Synthesis and structure of [Rh-6((PPr3)-Pr-i)(6)H-11(OH)][BAr4F](2)

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