A 'Cation-less' oxalate-based ferromagnet formed by neutral bimetallic layers: {[Co(H2O)(2)](3)[Cr(OX)(3)](2)(18-crown-6)(2)}(infinity) (OX = Oxalate dianion; 18-crown-6 = C12H24O6)

Coronado E; Galan-Mascaros JR; Marti-Gastaldo C

首页> 外文期刊>Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics >A 'Cation-less' oxalate-based ferromagnet formed by neutral bimetallic layers: {[Co(H2O)(2)](3)[Cr(OX)(3)](2)(18-crown-6)(2)}(infinity) (OX = Oxalate dianion; 18-crown-6 = C12H24O6)

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A 'Cation-less' oxalate-based ferromagnet formed by neutral bimetallic layers: {[Co(H2O)(2)](3)[Cr(OX)(3)](2)(18-crown-6)(2)}(infinity) (OX = Oxalate dianion; 18-crown-6 = C12H24O6)

机译：由中性双金属层形成的“无阳离子”草酸盐基铁磁体：{[Co（H2O）（2）]（3）[Cr（OX）（3）]（2）（18-crown-6）（2 ）}（无穷大）（OX =草酸盐双阴离子; 18冠6 = C12H24O6）

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Neutral layers of the bimetallic oxalate complex {[Co(H2O)(2)](3)[Cr-(ox)(3)](2)}infinity are formed in the presence of a crown ether and stabilized by hydrogen bonding. The resulting soluble ferromagnet orders at T-c = 7.4 K.

机译：在冠醚的存在下形成双金属草酸酯络合物{[Co（H2O）（2）]（3）[Cr-（ox）（3）]（2）}无穷大的中性层，并通过氢键稳定。在T-c = 7.4 K时产生的可溶性铁磁体有序。

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《Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics》 |2007年第20期|共3页
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Coronado E; Galan-Mascaros JR; Marti-Gastaldo C;
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1. A "Cation-less" oxalate-based ferromagnet formed by neutral bimetallic layers: {[Co(H2O)(2)](3)[Cr(OX)(3)](2)(18-crown-6)(2)}(infinity) (OX = Oxalate dianion; 18-crown-6 = C12H24O6) [J] . Coronado E, Galan-Mascaros JR, Marti-Gastaldo C Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2007,第20期

机译：由中性双金属层形成的“无阳离子”草酸盐基铁磁体：{[Co（H2O）（2）]（3）[Cr（OX）（3）]（2）（18-crown-6）（2 ）}（无穷大）（OX =草酸盐双阴离子; 18冠6 = C12H24O6）
2. Controlling the dimensionality of oxalate-based bimetallic complexes: The ferromagnetic chain {[K(18-crown-6)][Mn(bpy)Cr(ox)3]}infinity(18-crown-6=C12H24O6, ox = C2O42-, bpy=C10H8N2) [J] . Coronado E, Galan Mascaros JR, Marti-Gastaldo C Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 2007,第9a11期

机译：控制草酸酯基双金属配合物的尺寸：铁磁链{[K（18-crown-6）] [Mn（bpy）Cr（ox）3]}无穷大（18-crown-6 = C12H24O6，ox = C2O42- ，bpy = C10H8N2）
3. Synthesis and characterization of a soluble bimetallic oxalate-based bidimensional magnet: [K(18-crown-6)](3)[Mn-3(H2O)(4){Cr(ox)(3)}(3)] [J] . Coronado E, Galan-Mascaros JR, Marti-Gastaldo C Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2006,第5期

机译：可溶性双金属草酸盐基二维磁体的合成和表征：[K（18-crown-6）]（3）[Mn-3（H2O）（4）{Cr（ox）（3）}（3）]
4. Synthesis, Structure, and Magnetic Properties of the Oxalate-Based Bimetallic Ferromagnetic Chain {K(18-crown-6)Mn(H2O)2Cr(ox)3} (18-crown-6 = C12H24O6, ox = C2O42-) [O] . -1

机译：基于草酸的双金属铁磁性链的合成，结构和磁性{k（18-Crown-6） Mn（H2O）2Cr（Ox）3}（18-Crown-6 = C12H24O6，OX = C2O42 - ）

A 'Cation-less' oxalate-based ferromagnet formed by neutral bimetallic layers: {[Co(H2O)(2)](3)[Cr(OX)(3)](2)(18-crown-6)(2)}(infinity) (OX = Oxalate dianion; 18-crown-6 = C12H24O6)

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