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Strippable Coatings for Forensic Collection of Trace Chemicals from Surfaces

机译:可剥离涂层,用于从表面取证微量化学物

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Surface sampling for chemical analysis plays a vital role in applications like environmental monitoring, industrial hygiene, homeland security, and forensics. The standard surface sampling tool is a simple cotton gauze pad, but as techniques become more sensitive and the variety of analytes increases, gauze is failing to meet the needs of the community. Here, the collection of eight small molecules from glass surfaces with three different commercial spray-on, strippable coatings was demonstrated and their collection efficiency, as measured by gas chromatography/mass spectrometry, was compared to that of a standard cotton gauze. The three coating systems recovered 87-95% of the each compound, on average, from a nominal initial surface coverage of 0.1 g/m~2 per analyte. These recoveries were 3-fold better than the cotton gauze which had an average collection efficiency of 31%.
机译:用于化学分析的表面采样在诸如环境监测,工业卫生,国土安全和法证学等应用中起着至关重要的作用。标准的表面采样工具是一个简单的棉纱布垫,但是随着技术变得更加敏感和分析物种类的增加,纱布无法满足社区的需求。在此,我们展示了使用三种不同的商用可喷涂涂层从玻璃表面收集八种小分子的方法,并将通过气相色谱/质谱法测量的收集效率与标准棉纱网的收集效率进行了比较。三种涂层系统平均从每种分析物的名义初始表面覆盖率为0.1 g / m〜2的情况下,平均回收了每种化合物的87-95%。这些回收率比平均收集效率为31%的棉纱网高3倍。

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