A Discrete Supramolecular Conglomerate Composed of Two Saddle-Distorted Zinc(II)-Phthalocyanine Complexes and a Doubly Protonated Porphyrin with Saddle Distortion Undergoing Efficient Photoinduced Electron Transfer

摘要

Porphyrins(Por)and phthalocyanines(Pc)exhibit light-harvesting efficiency for producing charge-separated states as models of the reaction center in photosynthetic bacteria and photovoltaic cells for energy conversion.The use of supramolecular assemblies to model the functionality of the reaction center is an attractive and fruitful strategy to develop photofunctional materials and devices.