Selective conversion of cellobiose and cellulose into gluconic acid in water in the presence of oxygen, catalyzed by polyoxometalate-supported gold nanoparticles

摘要

Gold nanoparticles loaded onto Keggin-type insoluble polyoxometalates (Cs _xH _(3-x)PW _(12)O _(40)) showed superior catalytic performances for the direct conversion of cellobiose into gluconic acid in water in the presence of O _2. The selectivity of Au/Cs _xH _(3-x)PW _(12)O _(40) for gluconic acid was significantly higher than those of Au catalysts loaded onto typical metal oxides (e.g., SiO _2, Al _2O _3, and TiO _2), carbon nanotubes, and zeolites (H-ZSM-5 and HY). The acidity of polyoxometalates and the mean-size of the Au nanoparticles were the key factors in the catalytic conversion of cellobiose into gluconic acid. The stronger acidity of polyoxometalates not only favored the conversion of cellobiose but also resulted in higher selectivity of gluconic acid by facilitating desorption and inhibiting its further degradation. On the other hand, the smaller Au nanoparticles accelerated the oxidation of glucose (an intermediate) into gluconic acid, thereby leading to increases both in the conversion of cellobiose and in the selectivity of gluconic acid. The Au/Cs _xH _(3-x)PW _(12)O _(40) system also catalyzed the conversion of cellulose into gluconic acid with good efficiency, but it could not be used repeatedly owing to the leaching of a H ~+-rich hydrophilic moiety over long-term hydrothermal reactions. We have demonstrated that the combination of H _3PW _(12)O _(40) and Au/Cs _(3.0)PW _(12)O _(40) afforded excellent yields of gluconic acid (about 85 %, 418 K, 11 h), and the deactivation of the recovered H _3PW _(12)O _(40)-Au/Cs _(3.0)PW _(12)O _(40) catalyst was not serious during repeated use. Crazy glu: Cellulose was oxidized into gluconic acid by combining polyoxometalate (POM)-supported Au nanoparticles (NPs) and acidic POMs. Au-NP size and POM acidity are the determining factors in the selective oxidation of glucose and cellobiose.