Engineered hydrochar composites for phosphorus removal/recovery: Lanthanum doped hydrochar prepared by hydrothermal carbonization of lanthanum pretreated rice straw

摘要

Engineered hydrochar composites (EHC) were synthesized by hydrothermal carbonization (HTC) of lanthanum pretreated rice straw. The as-prepared composite with about 30% lanthanum content showed greater P removal potential than La(OH)_3, indicating the synergistic effect of hydrochar and lanthanum in P removal. The adsorption results showed that EHC showed great P adsorption capacities (>50 mg P g~(-1)) in the pH range of 2.5-10.5, and the presence of competing anions had little negative effects on P adsorption on EHC. The equilibrium time for P adsorption on EHC was considerably reduced under acid condition (12 h) compared to alkaline condition (48 h). The maximum adsorption capacity was 61.57 mg P g~(-1) according to Langmuir isotherms. These results suggested that EHC was highly effective in P adsorption in a wide range of pH and the presence of competing anions, thus EHC could be a promising adsorbent for phosphorus removal/recovery from wastewater.