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Condensed phase combustion travelling waves with sequential exothermic or endothermic reactions

机译:具有顺序放热或吸热反应的凝聚相燃烧行波

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The one-dimensional propagation of a combustion wave through a premixed solid fuel for two-stage kinetics is studied. We re-examine the analysis of a single reaction travelling-wave and extend it to the case of two-stage reactions. We derive an expression for the travelling wave speed in the limit of large activation energy for both reactions. The analysis shows that when both reactions are exothermic, the wave structure is similar to the single reaction case. However, when the second reaction is endothermic, the wave structure can be significantly different from single reaction case. In particular, as might be expected, a travelling wave does not necessarily exist in this case. We establish conditions in the limiting large activation energy limit for the non-existence, and for monotonicity of the temperature profile in the travelling wave.
机译:研究了燃烧波在两级动力学中通过预混合固体燃料的一维传播。我们重新检查单个反应行波的分析,并将其扩展到两阶段反应的情况。我们推导了两个反应在大活化能极限下的行波速度表达式。分析表明,当两个反应都放热时,波的结构类似于单个反应的情况。然而,当第二反应是吸热的时,波结构可能与单个反应情况明显不同。特别地,如所预期的,在这种情况下行波不一定存在。我们为不存在的以及行波中温度曲线的单调性而在限制较大的激活能量极限时建立了条件。

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