This study investigates the formation of pitting defects on two phosphated low alloy steel rods containing, respectively, 1.1 percent Si and 1 percent Cr. Test steels included a phosphated rod, an as-rolled rod, and a lab-melted ingot. An optical microscope (O M) or a scanning electron microscope (SEM) with energy dispersive spectrometer (EDS) were employed to analyze the surface morphology and the cross-sectional microstructure of the individual stage during manufacturing process. The results indicated that the pitting defects came from a corrosion of the substrate adjacent to residual Si/Cr-containing iron oxide before phosphating. After phosphating, the small pits became large pits or large area corrosion zones visible as defects to the human eye.
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