The process developed consists of higher alcohols washing with methanol, dehydration to remove methanol, and following ammoniac leaching of copper for 100-125 h. The kinetics, temperature effect (20-27 deg C), reagent concentrations, and a ration of m_S: m_L=1:(3?5) for fullness of copper leaching in nitrate-, sulfate-, and carbonate-ammoniac solutions are compared. Carbonate-ammoniac and particularly nitrate-ammoniac media proved to be preferable. They permit o use the solutions produced (with content up to 80-85 g/l copper) to have a fresh catalyst. The copper extraction degree is 92-95 percent. The deposit contains HCrO_2, BaO, SiO_2, and CuO impurity, and after leaching it can be useful as a component of welding fluxes or abrasive materials.
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机译：开发的方法包括用甲醇洗涤高级醇，脱水除去甲醇，然后氨浸铜100-125小时。比较了动力学，温度效应（20-27摄氏度），试剂浓度以及在硝酸盐，硫酸盐和碳酸盐氨溶液中铜浸出饱满度的m_S：m_L = 1：（3？5）的比率。 。碳酸盐-氨，特别是硝酸盐-氨介质被证明是优选的。它们允许使用产生的溶液（铜含量最高为80-85 g / l）具有新鲜的催化剂。铜提取度为92-95％。该沉积物包含HCrO_2，BaO，SiO_2和CuO杂质，浸出后可用作焊剂或磨料的成分。
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