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首页> 外文期刊>鉄と鋼/Journal of the Iron and Steel Institute of Japan. >Microstructural Analysis of Rust Layers on Weathering Steels Exposed at Rural and Coastal Areas
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Microstructural Analysis of Rust Layers on Weathering Steels Exposed at Rural and Coastal Areas

机译:在农村和沿海地区暴露的耐候钢锈层的显微组织分析

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Weathering steel has been widely used for the bridge materials because of its superior atmospheric corrosion resistance. It has been, however, pointed out that the amounts of corrosion are greater used in coastal area than rural area. In order to clarify the differences of corrosion resistance between rural and coastal area, rust layers were analyzed in details by combining with FIB (Focused Ion Beam) and electron microscope. Analytical results indicate as follows:Inner layer of the rust exposed in rural area consists of multiple layers and thickness of each layer is less than 2 #mu#m. These layers have dif-ferent composition and degree of enrichment in alloying elements, especially chromium. Though these layers consist of mainly FeOOH fine particles, crystalline FeOOH layer exists between fine particle layers. Rust layer exposed in coastal area did not show such multiple-layer structure. The layer consists of crystalline #beta#-FeOOH and FeOOH fine particles. The crystalline #beta#-FeOOH is not a single crystal but is an aggregation of ordered fine rust particles. A size of the fine particles of rust exposed in coastal area is not much different from that exposed in rural area. Major differences existed are structure and packing state of fine rust particles.
机译:耐候钢由于其优异的耐大气腐蚀性能而被广泛用于桥梁材料。然而,已经指出,沿海地区使用的腐蚀量比农村地区要多。为了弄清农村地区和沿海地区的耐蚀性差异,结合FIB(聚焦离子束)和电子显微镜对锈层进行了详细分析。分析结果表明:农村暴露的铁锈内层由多层组成,每层厚度小于2#μm。这些层在合金元素(尤其是铬)中具有不同的组成和富集程度。尽管这些层主要由FeOOH细颗粒组成,但是结晶FeOOH层存在于细颗粒层之间。在沿海地区暴露的锈层没有表现出这种多层结构。该层由结晶的#beta#-FeOOH和FeOOH细颗粒组成。晶体β-FeOOH不是单晶,而是有序细锈颗粒的聚集体。在沿海地区暴露的锈细颗粒的大小与在农村地区暴露的锈没有太大差异。存在的主要区别是细锈颗粒的结构和堆积状态。

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