Synthesis and spectral characterisation of organotin(IV) 1,3,5-triazine-2,4,6-trithiolato complexes, including the crystal structures of 1,3,5-(R_3Sn)_3C_3N_3S_3 (R=Me, Ph)

摘要

Novel organotin(IV) 1,3,5-triazine-2,4,6-trithiolato complexes: (R_3Sn)_3C_3N_3S_3, (R=Ph, BZ, Me, Bu) and (R_2Sn)_3(C_3N_3S_3)_2, (R=Ph, Me) have been prepared and characterised by elemental analysis, FT-IR, Mossbauer and multinuclear NMR spectroscopy. HTe crystal and molecular structures of 1,3,5-(R_3Sn)_3C_3N_3S_3 (R=Me, Ph) have been determined and contan tetrahedral organotin units in a 'manxane' arrangement about the central triazine. There are no close intermolecular interactions.