Interfacial effect of surface modified TiO_2 and SiO_2 nanoparticles reinforcement in the properties of wood polymer clay nanocomposites

摘要

A B S T R A C T In this paper, surface modification and characterization of TiO_2, SiO_2 nanoparticles and their role on the physical properties of wood styrene acrylonitrileanoclay composites were investigated. Simul wood (Bombex ceiba L.) was used for preparation of wood polymer nanocomposites by impregnation of intercalating mixture of styrene acrylonitrile co-polymer (molar ratio 2:3) and combination of nanofillers TiO_2, SiO_2 and nanoclay. For the improvement in nanoparticles dispersion and increasing possible interactions among nanoparticles, polymer matrix and wood, the surface of TiO_2 and SiO_2 nanoparticles was modified with y-methacryloyloxy trimethyl silane, a silane coupling agent. The characterization of the composites was done by using FT-IR, XRD, and TGA studies. The exfoliation of nanoclay and the homogeneous dispersion of nanoparticles in SAN polymer matrix on cell wall of wood was studied by TEM. The flexural, tensile properties were improved. UV stability was evaluated by photo-induced weight loss (%), FTIR, loss in mechanical properties, and scanning electron microscopy (SEM). The resultant wood polymer nanocomposites (WPNC) exhibited an improvement in hardness. The overall improvement in properties has been achieved for the wood/SAN sample treated with 0.5% each of TiO_2, SiO_2 and nanoclay.