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Development of Ultra-High Molecular Weight Polyethylene (UHMWPE) Coating by Cold Spray Technique

机译:冷喷涂技术开发超高分子量聚乙烯(UHMWPE)涂料

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摘要

Ultra-high molecular weight polyethylene or UHMWPE is an extremely difficult material to coat with, as it is rubbery and chemically very inert. The Cold Spray process appears to be a promising alternative processing technique but polymers are in general difficult to deposit using this method. So, attempts to develop UHMWPE coatings were made using a downstream injection cold spray technique incorporating a few modifications. A conventional cold spray machine yielded only a few deposited particles of UHMWPE on the substrate surface, but with some modifications in the nozzle geometry (especially the length and inner geometry) a thin coating of 45 mu m on Al substrate was obtained. Moreover, experiments with the addition of fumed nano-alumina to the feedstock yielded a coating of 1-4 mm thickness on Al and polypropylene substrates. UHMWPE was seen to be melt crystallized during the coating formation, as can be seen from the differential calorimetry curves. Influence of nano-ceramic particles was explained by observing the creation of a bridge bond between UHMWPE particles.
机译:超高分子量聚乙烯或UHMWPE是一种极难涂覆的材料,因为它具有橡胶状且化学性质非常惰性。冷喷涂工艺似乎是一种有前途的替代加工技术,但是使用这种方法通常很难沉积聚合物。因此,尝试使用结合了一些改进的下游喷射冷喷涂技术来开发UHMWPE涂层。常规的冷喷涂机仅在基底表面上产生少量的UHMWPE沉积颗粒,但是在喷嘴几何形状(特别是长度和内部几何形状)上进行了一些修改,在Al基底上获得了45微米的薄涂层。此外,向原料中添加气相纳米氧化铝的实验在Al和聚丙烯基材上产生了1-4 mm厚度的涂层。从差示量热曲线可以看出,UHMWPE在涂层形成过程中熔融结晶。纳米陶瓷颗粒的影响通过观察UHMWPE颗粒之间桥键的产生来解释。

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