首页> 外文期刊>Journal of thermal analysis and calorimetry >Apparent molar volume and apparent molar adiabatic compressibility of 2-hydroxy-5-methyl acetophenone in N,N-dimethylformamide at different temperatures (Conference Paper)
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Apparent molar volume and apparent molar adiabatic compressibility of 2-hydroxy-5-methyl acetophenone in N,N-dimethylformamide at different temperatures (Conference Paper)

机译:N,N-二甲基甲酰胺中不同温度下2-羟基-5-甲基苯乙酮的表观摩尔体积和表观摩尔绝热压缩性(会议论文)

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摘要

The speed of sound and density of 2-hydroxy-5-methyl acetophenone in dimethylformamide have been measured over the range of temperatures 25-40 °C. From the experimentally determined data, values of apparent molar volume (V _φ), adiabatic compressibility (β _s), apparent molar adiabatic compressibility (K _(s,φ)) and their limiting values have been computed. Values at infinite dilution provide information regarding solute-solvent interaction. The density and velocity increases with increase in concentration and decreases with increase in temperature. These results have been analyzed in terms of molecular interactions between acetophenone and dimethylformamide.
机译:在25-40°C的温度范围内测量了声速和二甲基甲酰胺中2-羟基-5-甲基苯乙酮的密度。根据实验确定的数据,已计算出表观摩尔体积(V_φ),绝热压缩率(β_s),表观摩尔绝热压缩率(K _(s,φ))及其极限值。无限稀释的值提供了有关溶质与溶剂相互作用的信息。密度和速度随浓度增加而增加,随温度增加而减少。根据苯乙酮和二甲基甲酰胺之间的分子相互作用分析了这些结果。

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