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首页> 外文期刊>Coke and chemistry >Rheological properties of coal suspension sludge in the presence of a flocculant
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Rheological properties of coal suspension sludge in the presence of a flocculant

机译:絮凝剂存在下煤悬浮液的流变特性

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1. To dilute BS-30F before use, one can employy technical water from coal-dressing plant in the industrial Donbass of total hardness <= 9.4 mg-eq/liter and pH in the range 7.8-9.2. Selective flocculation with BS-30F is best performed with typical circulating water of total hardness from 8 to 17 mg-eq/liter and pH = 7.8-9.2. 2. The time required for the total deposition of a coal sludge is dependent on the grade of coal and the floeculant flow rate. 3. When the floeculant contacts the solid, there are hydrophobic interactions of the polymer globules with the surfaces of the coal particles; chains of polymer globules are formed that link the particles into aggregates. In the presence of electrolytes in the liquid, the chains of polymer globules of floeculant coagulate and become rubbery filaments; the bonds between the coal grains are strengthened and relatively large and reasonably strong floccules arise. As the floeculant concentration increases, the electrochemical potential of any grade of coal rises in the positive sense, and the more so the more metamorphosed the coal. 4. When a coal suspension is mixed with the floeculant, an emulsifier is transferred from the polymer globules to the liquid: the potash soap of disproportionated rosin, which is then adsorbed on the mineral grains and favors their stabilization. 5. There is the best value for the Reynolds number (dependence of the selective flotation performance on the mixing intensity) where the propellor mixer is used. Coal floccules begin to form after 15 sec contact of the floeculant with the solid phase. The best time for mixing the sludge with BS-30F has been determined. 6. We consider that a transitional form of structure may arise on structuring a dispersed system additional to the known ones: the flocculation-condensation form. 7. An important resultant parameter for the properties of the liquid in a coal sludge is the resistance to a moving body, which combines the viscosity, the density, and the confinement of the working medium. To reduce the resistance to the motion of coal grains on dressing, it is proposed to reduce the viscosity of the liquid phase by treating it with selective floeculant BS-30F, in which the emulsifier (potash soap of disproportionated rosin) is a surfactant.
机译:1.要在使用前稀释BS-30F,可以使用工业Donbass中选煤厂的工业用水,总硬度<= 9.4 mg-eq / L,pH值在7.8-9.2。用BS-30F进行的选择性絮凝最好在总硬度为8至17 mgeqeq /升且pH = 7.8-9.2的典型循环水中进行。 2.煤泥全部沉积所需的时间取决于煤的等级和絮凝剂的流速。 3.当絮凝剂接触固体时,聚合物小球与煤颗粒的表面之间存在疏水相互作用。形成了聚合物球的链,将颗粒连接成聚集体。在液体中存在电解质的情况下,絮凝剂的聚合物小球链凝结并变成橡胶状长丝。煤粒之间的结合得到加强,并且产生了较大且相当坚固的絮凝物。随着絮凝剂浓度的增加,任何等级的煤的电化学势均从正方向上升,并且越多,煤的变质性就越大。 4.当将煤悬浮液与絮凝剂混合时,乳化剂会从聚合物小球转移到液体中:歧化松香的钾盐肥皂,然后被吸附在矿物颗粒上并有利于其稳定。 5.使用螺旋桨混合器时,雷诺数(取决于选择性浮选性能与混合强度的关系)的最佳值。絮凝剂与固相接触15秒后,开始形成煤絮凝物。确定了将污泥与BS-30F混合的最佳时间。 6.我们认为,在构造除已知系统之外的分散系统时,可能会出现结构的过渡形式:絮凝冷凝形式。 7.对于煤泥中的液体性质而言,重要的合成参数是对移动体的抵抗力,该抵抗力结合了粘度,密度和工作介质的限制。为了降低对选矿中的煤粒运动的抵抗力,提出了通过用选择性絮凝剂BS-30F处理来降低液相的粘度的方法,其中乳化剂(歧化松香的钾皂)是表面活性剂。

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