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Kinetics of Formation of Bitumens upon Thermal Treatment of Coals

机译:煤热处理后形成沥青的动力学

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The thermal treatment of coal blends prior to coking together with other measures (partial briquetting, stamping of a coal blend, selective pulverization of coal components) is regarded as one of the most promising paths for increasing the efficiency of the laminar coking process (1). Upon thermal treatment of coal blends their moisture decreases and the density of the charge increases, which reduces the consumption of heat in the process and increases the capacity of coke ovens. Moreover, the thermal activation of the most mobile constituents of coal organic matter (bitumens) leads to the improvement of the caking power of coal blends, which contributes to the upgrading of coke quality even when the amount of weakly caking coals in mixes is increased.As has been pointed out by Ruschev (2), the problem of bitumens and their role in the caking of coals is one of the long-standing problems in coal chemistry. As far back as the turn of the century (at the end of the 19th and the beginning of the 20th century) it was established that the removal of bitumens from coal results in the loss of caking properties and their addition to noncaking coals stimulates the formation of caking capacity. According to Dryden (3), the yield of bitumens increases upon extraction of coals heated in an inert medium at 200-400 deg C.
机译:焦化之前对煤混合物的热处理以及其他措施(部分压块,对煤混合物进行冲压,对煤成分进行选择性粉碎)被认为是提高层状焦化效率的最有希望的途径之一(1) 。在对煤混合物进行热处理后,其水分减少,装料密度增加,这减少了过程中的热量消耗并提高了焦炉的能力。此外,煤有机物(沥青)中最易移动的成分的热活化导致混合煤的结块能力提高,即使增加混合中弱粘结性煤的量,也有助于提高焦炭质量。正如Ruschev(2)所指出的那样,沥青的问题及其在煤结块中的作用是煤化学中长期存在的问题之一。早在本世纪初(在19世纪末和20世纪初),人们已经确定从煤中去除沥青会导致结块性能下降,并且将其添加到非结块煤中会刺激其形成。结块能力。根据Dryden(3)的说法,沥青的产量会随着在惰性介质中加热200-400摄氏度的煤的提取而增加。

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