Application of trace metal anomalies for recognition of petroleum prospects in surface sediments of Kutch and Saurashtra Basins, India

摘要

Seepage of hydrocarbons, either as macroseepage or microseepage, can set up near-surface oxidation-reduction zones that favour the development of a diverse array of chemical and mineralogic changes. In this study trace metal alterations were mapped that appear to be associated with hydrocarbon microseepages in the oil/gas fields. A total of 210 soil samples were collected from near surface sediments of Kutch and Saurashtra Basins, India. The soil samples were collected from a depth of 2-2.5 m. The paper reports the chemical alterations associated with trace metals in soils that are related to hydrocarbon microseepages above the Kutch and Saurashtra Basins, India. The soil samples for trace metals; Scandium (Sc), Vanadium (V), Chromium (Cr), Cobalt (Co), Nickel (Ni), Copper (Cu), Zinc (Zn), Barium (Ba) and Strontium (Sr) were analyzed using Inductively Coupled Plasma-Mass Spectrometry (ICP-MS). The concentrations of the trace elements ranged between for Sc (12.69 to 21.91 ppm), V (109.20 to 436.05 ppm), Cr (87.15 to 481.57 ppm), Co (18.25 to 64.31 ppm), Ni (57.55 to 263.15 ppm), Cu (44.88 to 143.96 ppm), Zn (137.60 to 502.31 ppm), Ba (149.27 to 921.46 ppm) and Sr (143.93 to 425.63 ppm) were obtained. It was observed that trace elements concentrations were tremendously increased when compared with normal concentration in the soils. The adsorbed soil gas analysis showed the presence of high concentrations of ΣC_(2+) (C _2H_6, C_3H_8 and n-C_4H _(10)) ranged between 1 to 121 ppb respectively. Integrated studies of trace elements over adsorbed light gaseous hydrocarbon (ΣC_(2+)) anomalies showed good correlation. The carbon isotopic composition of δ~(13)C_1 of the samples ranges between - 36.6 ‰ to -22.7‰ (Pee Dee Belemnite) suggest thermogenic source for hydrocarbon gases. The increase in trace metal concentrations near oil/gas producing areas, suggests that soil chemical change to a reducing environment, presumably due to the influence of hydrocarbon microseepage, which could be applied with other geo-scientific data to identify areas of future hydrocarbon exploration in the frontier areas.