Photoreaction of gold ions from potassium gold cyanide wastewater using solution-combusted ZnO nanopowders

摘要

Photoreduction of gold ions from potassium gold cyanide wastewater was tried using the ZnO nanopowder which was synthesized by a unique solution combustion method (SCM). The SCM produced instantaneous high pressure and high temperature (1500-1800 deg C) conditions which are desirable to obtain high quality ZnO nanopowders, even though it was not intentionally heated at higher than 100 deg C during the synthesis reaction. The high crystalline quality of the ZnO nanopowder seemed to result in high efficiency of gold recovery compared to other commercial photocatalysts such as P-25 TiO_2 nanopowder (Degussa). The wastewater contains many kinds of ions such as K, P, Au, Na, Ni, Cu and Zn ions. Only the gold ions were selectively recovered out of these ions. The gold recovery efficiency of the SCM ZnO nanopowder was about 8.6 folds higher than that of the P-25 TiO_2 nanopowder. The very high selectivity of Au~(3+) ions could be explained by the reduction potential which is placed near the edge of valence band.