Gelcasting of alumina suspensions containing nanoparticles with glycerol monoacrylate

摘要

An acrylic monomer of low toxicity containing two hydroxyl groups has been synthesized and used for gelcasting in water. The results have been compared to those achieved with the use of a commercially available monomer (2-hydroxyethyl acrylate). Due to the chemical structure of the synthesized monomer, no addition of the crosslinking agent was necessary for gelation and similar results in terms of rheology of suspensions, density and microstructure of the bodies were obtained with respect to those obtained with the commercial monomer. However, higher time for gelation was observed. Two alumina powders with very different particle sizes were used in this study: a commercial submicron-sized powder (d_(50) = 0.35 (mum) and a nanometer-sized alumina obtained by freeze-drying from aluminum sulphate solutions. The Theological behavior of concentrated suspensions was studied in order to establish their stability and to analyse the effect of the different monomers used in the process. Once the suspensions were optimized, the influence of the size of the powder on the gelation process was studied. The sintered density of submicrometer-sized alumina was higher (99percent) than that measured when the bimodal suspension was used due to the difficulty to obtain highly concentrated suspensions from nanometric powder.