An original heterodinuclear VO2+,Gd3+ complex with a nonet ground state

摘要

Reaction of the vanadyl complex of N,N'-bis(3-methoxysalicylidene)-1 ,2-diamino-2-methylpropane (H2L) with Gd(NO3)(3) . 5H(2)O yielded a dinuclear complex (LVOGdIII)-O-IV(NO3)(3) .(CH3)(2)CO which presents a ferromagnetic interaction between the paramagnetic (S = 1/2) vanadyl and the gadolinium (S = 7/2) ions, with a J value of 1.3 cm(-1). [References: 20]