A novel three-dimensional triangular organic-inorganic hybrid network self-assembled by mononuclear [Mn)4,4′-bipyridine)_2-(H_2O_4]~(2+) cations and rich solvate 4,4′-bipyridine molecules through hydrogen-bonding and #pi#-#pi# interactions

摘要

The solid compound formulated as [Mn(4,4′-bpy)_2-(H_2O)_4][ClO_4]_2.(4,4′-bpy)_4 (bpy=bipyridine) has been shown by single-crystal structural analysis to be a three-dimensional network with triangular channels, which are constructed by mononuclear [Mn(4,4′-byp)_2(H_2O)_4]~(2+) cations and 4,4′-bpy molecules through extensive hydrogen-bonds and #pi#-#pi# interactions.