A facile access to rac ansa-lanthanocene alkyl complexes with an ether-bridged indenyl ligand and crystal structure of rac-[O(CH_2CH_2C_9H_6)_2]YCH_2SiMe_3

Changtao Qian; Gang Zou; Jie Sun

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A facile access to rac ansa-lanthanocene alkyl complexes with an ether-bridged indenyl ligand and crystal structure of rac-[O(CH_2CH_2C_9H_6)_2]YCH_2SiMe_3

机译：轻松访问具有醚桥茚配基和rac- [O（CH_2CH_2C_9H_6）_2] YCH_2SiMe_3的晶体结构的rac ansa-镧系茂金属烷基络合物

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摘要

Pure rac ansa-lanthanocene alkyl complexes [O(CH_2CH_2C_9H_6)_2]LnCH_2SiMe_3 (Ln=Y 1, Lu 2) are stereoselectively formed dictated by the nonbonded interactions between the six-membered portion of the indenyl moiety and the alkyl group.

机译：由茚基部分的六元部分与烷基之间的非键合相互作用决定了立体选择性地形成纯的rac ansa-镧系茂金属茂[O（CH_2CH_2C_9H_6）_2] LnCH_2SiMe_3（Ln = Y 1，Lu 2）。

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《Journal of the Chemical Society, Dalton Transactions. Inorganic Chemistry》 |1999年第4期|共2页
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Changtao Qian; Gang Zou; Jie Sun;
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1. A facile access to rac ansa-lanthanocene alkyl complexes with an ether-bridged indenyl ligand and crystal structure of rac-[O(CH_2CH_2C_9H_6)_2]YCH_2SiMe_3 [J] . Changtao Qian, Gang Zou, Jie Sun Journal of the Chemical Society, Dalton Transactions. Inorganic Chemistry . 1999,第4期

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A facile access to rac ansa-lanthanocene alkyl complexes with an ether-bridged indenyl ligand and crystal structure of rac-[O(CH_2CH_2C_9H_6)_2]YCH_2SiMe_3

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