Synthesis, X-ray crystal structure and spectroscopic characterization of the new dithiolene [Pd(Et(2)timdt)(2)] and of its adduct with molecular diiodine [Pd(Et(2)timdt)(2)]center dot I-2 center dot CHC](3) (Et(2)timdt = monoanion of 1,3-diethylimida

摘要

The first Pd dithiolene [Pd(Et(2)timdt)(2)] 4a belonging to the new class of metal dithiolenes deriving from the R1/2timdt (R1/2timdt = monoanion of 1,3-dialkylimidazolidine-2,4,5-trithione) ligand has been characterised by X-ray crystal structure determination on a single crystal [monoclinic, space group P2(1), a = 9.545(2), b = 5.417(2), c = 20.093(4) Angstrom, beta = 93.40(2)degrees, Z = 2], UV-VIS-NIR, diffuse solid state reflectance, FTIR, FT-Raman spectroscopies, solid state C-13 NMR and cyclic voltammetry and the results have been comparatively discussed with those obtained for the analogous [Ni(Et(2)timdt)(2)] 4b. The UV-VIS-NIR spectrum of 4a is dominated by a very intense absorption band at 1010 nm (epsilon = 70 000 dm(3) mol(-1) cm(-1)). The NIR features of 4a and 4b have been examined on the basis of the electronic structure of their ground-state configurations, investigated by DFT calculations. The co-crystallisation of 4a with I-2 yielded the [Pd(Et(2)timdt)(2)].I-2.CHCl3 6 adduct [monoclinic, space group C2/m, a = 21.724(9), b = 12.901(4), c = 11.004(6) Angstrom, beta = 102.83(4)degrees, Z = 4]. No short metal-metal interaction was observed in both 4a and 6 (Pd ... Pd 5.42 Angstrom in 4a and 5.25 Angstrom in 6), since each palladium ion is almost 'sandwiched' between two imidazolidine rings of parallel adjacent molecules. [References: 49]