Stability and coordination mode of complexes of polyphosphates and polymetaphosphates with copper(II) ions in aqueous solution-potentiometric, spectral and theoretical studies

摘要

Complexes of copper(II) with a number of polyphosphate and polymetaphosphate anions have been studied in aqueous solutions by potentiometric, spectroscopic and theoretical methods. Stability constants of the complexes have been determined as well as their coordination modes. Results of the equilibrium studies provided evidence for the formation of ML, MHL and ML(OH)_x type complexes with the ligands studied. The length of the polyphosphate chain was found to affect the oxygen atom charge that is reflected in the stability constants of the ML type complexes. Moreover, the stability of the complex is also influenced by the spatial arrangement of the phosphate groups in phosphates and metaphosphates. The spectral parameters observed for certain complexes have permitted us to deduce the inner coordination sphere of the studied complexes.