The liquid junction potential in potentiometric titrations. IX. The calculation of potentials across liquid junctions of the type, AY vertical bar AY+BYz(B)+HY+A(y)L, for Emf cells where strong or weak complexes are formed, respectively, at [Y-] = C

摘要

In the present part, potential functions are derived for the calculation of the total potential anomalies, Delta E-B and Delta E-H, for Emf cells where strong or weak complexes are formed, respectively. A weak or strong electrolyte is considered to be used as complexing agent (A(y)L), respectively, at the experimental condition, [Y-] = C mol(.)L(-1), constant. The cells have indicator electrodes reversible to Bz(B)+ (cell B) and H+ ions (cell H), respectively.