Osmotic Coefficients and Activity Coefficients of Nonaqueous Electrolyte Solutions. Part 4. Lithium Bromide, Tetrabutylammonium Bromide, and Tetrabutylammonium Perchlorate in Acetone

摘要

Vapor pressure lowering by the addition of lithium bromide (0.03-0.8m), tetrabutylammonium bromide (0.01-0.8m), and tetrabutylammonium perchlorate (0.02-3.6m) to acetone was measured at 25 deg C with high precision. The experimental data of the corresponding osmotic coefficients are compared to those obtained by the use of Pitzer equations and chemical model calculations. Mean activity coefficients are derived from th osmotic coefficients.