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Determination of chemical elements in airborne particulate matter collected at Lembang, Indonesia by particle induced X-ray emission

机译:粒子诱导的X射线发射法测定印度尼西亚连邦收集的空气传播颗粒物中的化学元素

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摘要

Monitoring the air quality in ambient air is an important step for assessing the air pollution level in one region and its impact to the human health. In this study, the determination of chemical elements concentrations in airborne particulate matter collected in suburban area of Lembang, Indonesia was carried out. Samples were collected using a Gent stacked filter unit sampler in two size fractions of <2.5 μm (fine) and 2.5-10 μm (coarse). Sampling was conducted twice a week for 24 h from January 2008 to June 2009 and 123 pairs of samples were collected. Black carbon was determined by reflectance and chemical elements analysis were performed using particle induced X-ray emission (PIXE). PIXE as one of ion beam analysis techniques is suitable for analyzing particulate matter for its multielemental analysis with good limits of detection. Results showed that none of daily concentrations of PM_(2.5) and PM_(10) exceeded the 24 h Indonesian NAAQS for PM_(2.5) and PM_(10). Chemical elements such as Mg, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, As, Hg and Pb were determined and the correlation between these elements was reported in order to understand the anthropogenic sources of particulate matter.
机译:监测环境空气中的空气质量是评估一个地区的空气污染水平及其对人类健康影响的重要步骤。在这项研究中,对印度尼西亚伦邦郊区收集的空气中颗粒物中的化学元素浓度进行了测定。使用Gent堆叠式过滤器单元采样器以小于2.5μm(精细)和2.5-10μm(粗略)的两个尺寸分数收集样品。从2008年1月到2009年6月,每周进行两次采样,持续24小时,收集了123对样本。通过反射率确定黑碳,并使用粒子诱导的X射线发射(PIXE)进行化学元素分析。 PIXE作为离子束分析技术之一,适用于对颗粒物进行多元素分析并具有良好的检测极限的分析方法。结果显示,PM_(2.5)和PM_(10)的每日PM_(2.5)和PM_(10)浓度均未超过印尼24小时NAAQS。测定了Mg,V,Cr,Mn,Fe,Co,Ni,Cu,Zn,As,Hg和Pb等化学元素,并报告了这些元素之间的相关性,以便了解颗粒物的人为来源。

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