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Measurement of water vapor line strengths in the 1.4-2.7 mu m range by tunable diode laser absorption spectroscopy

机译:通过可调二极管激光吸收光谱法测量1.4-2.7μm范围内的水蒸气线强度

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Line strengths of nine water vapor absorption lines in the wavelength range between 1.37 and 2.71 mu m with line strengths of 10(-23)-10(-2) cm/molecule have been measured using direct tunable diode laser absorption spectroscopy (dTDLAS). Four different light sources were used: three distributed feedback (DFB) diode lasers with wavelengths of 1.37 mu m, 2.55 mu m and 2.71 mu m for measuring one application-specifically selected absorption line with each laser, and a vertical-cavity surface-emitting laser (VCSEL) radiating around 1.39 mu m for the measurement of six further absorption lines. Despite the different light sources and line strengths, a uniform measurement and data evaluation method was developed and applied to all lines, and the experimental set-up was kept as similar as possible. This allows a thorough and uniform uncertainty analysis and evaluation of the contributions of the individual experimental parameters to the uncertainty of the derived line strengths. A comprehensive and transparent uncertainty analysis is given for the measurements. Uncertainties of our measured line strengths are in the 1.1-2.5% range (k=2, 95% confidence level). Our measured line strength values agree well with line strengths in the HITRAN 2012 database and other literature sources, we realized lower uncertainties up to a factor of 5-10. (C) 2015 Elsevier Ltd. All rights reserved.
机译:使用直接可调二极管激光吸收光谱法(dTDLAS)测量了9条水蒸气吸收线的线强度,该线的波长范围在1.37和2.71μm之间,线强度为10(-23)-10(-2)cm /分子。使用了四种不同的光源:三个波长分别为1.37μm,2.55μm和2.71μm的分布式反馈(DFB)二极管激光器,用于测量每个激光器的一个特定于应用的吸收线,以及垂直腔表面发射激光(VCSEL)辐射约1.39微米,用于测量另外6条吸收线。尽管光源和线路强度不同,但仍开发了一种统一的测量和数据评估方法并将其应用于所有线路,并且实验设置尽可能保持相似。这样就可以进行彻底,统一的不确定性分析,并评估各个实验参数对得出的线强度的不确定性的影响。对测量进行了全面而透明的不确定性分析。我们测得的线强度的不确定度在1.1-2.5%范围内(k = 2,置信度为95%)。我们测得的线强度值与HITRAN 2012数据库和其他文献资料中的线强度非常吻合,我们意识到不确定性降低了5-10倍。 (C)2015 Elsevier Ltd.保留所有权利。

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