Pressure effects on inter- and intramolecular vibrations in hydrogen-bonded L-ascorbic acid crystal

摘要

Pressure effects on the Raman spectra due to the inter- and intramolecular vibrations of the L-ascorbic acid crystal were studied. The intensity of the Raman bands due to the intermolecular vibrations varies in three different ways by application of pressure. The bands of the first group become stronger, those of the second one become weaker and the third group shows no prominent change in their intensity with increasing pressure. The bands due to the intermolecular vibrations show a blue shift, while the bands due to the intramolecular vibrations shift to the blue or red depending on the vibrational modes by application of pressure. The bands assigned to the O-H stretching vibrations shift to the red, the bands assigned to the C = O and C = C stretching vibrations shift a little to the red and the bands assigned to the other vibrations shift to the blue under high pressure. The following conclusions were derived. (1) The hydrogen bonds forming helixes become stronger and the isolated hydrogen bond becomes weaker with increasing pressure. (2) The bands of the first group owing to the intermolecular vibrations are ascribed to the vibrations related to the helix hydrogen bonds and the second group bands to the isolated hydrogen bond. (3) The C = O stretching vibration couples with the C = C stretching vibration. (4) The phase transitions take place at 1.8 and 4 GPa in the crystal. Copyright (c) 2007 John Wiley & Sons, Ltd.