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Analysis of the phonon spectrum in the titanium oxyhalide TiOBr

机译:卤氧化钛TiOBr中的声子光谱分析

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We present the electrodynamic response of TiOBr, which undergoes a transition to a spin-singlet ground state for temperatures below T-Cl =: 28 K. The temperature evolution of the phonon anomalies indicates, like in TiOCl, an extended fluctuation regime, extending well above T-Cl. At low frequencies, the spectral weight is progressively suppressed by decreasing the temperature, suggesting the formation of a spin-gap and a considerable electron-phonon coupling. A comparison of the two oxyhalides shows a weaker interplane coupling and reduced dimensionality for TiOBr that enhances fluctuations and shifts the ordering temperatures to lower values. In the fluctuation regime the temperature dependences of some phonon parameters track the temperature evolution of the magnetic susceptibility.
机译:我们介绍了TiOBr的电动力响应,当温度低于T-Cl =:28 K时,它经历了转变为自旋单基态。声子异常的温度演变表明,像在TiOCl中一样,扩展了涨落范围,扩展良好高于T-Cl。在低频下,通过降低温度来逐步抑制频谱权重,这表明形成了自旋间隙和相当大的电子-声子耦合。两种卤氧化物的比较显示出TiOBr的平面间耦合较弱,尺寸减小,这会增加波动并将订购温度移至较低值。在起伏状态下,某些声子参数的温度相关性会跟踪磁化率的温度变化。

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