Dissolved oxygen control and monitoring implementation in the liquid lead-bismuth eutectic loop: HELIOS

摘要

A 12 m tall LBE coolant loop, named as HELIOS, has been developed by thermal-hydraulic scaling of the PEACER-300MWe. Thermo-hydraulic experiment and materials test are the principal purposes of HELIOS operation. In this study, an yttria stabilized zirconia (YSZ) based oxygen sensor that was hermetically sealed for long-term applications using the electromagnetically swaged metal-ceramic joining method, have been developed for high temperature oxygen control application over a long period of time. The rugged electrode design has been calibrated to absolute metal-oxide equilibrium by using a first principle of detecting pure metal-oxide transition using electrochemical impedance spectroscopy (EIS). During the materials tests in HELIOS, dissolved oxygen concentration was administered at the intended condition of 10(-6) wt% by direct gas bubbling with Ar + 4%H-2, Ar + 5%O-2 and/or pure Ar while corrosion tests were conducted for up to 1000 It with inspection after each 333 It. During the total 1000 h corrosion test, oxygen concentration was measured by oxygen sensor. The result confirmed that the direct gas bubbling method is a viable and practical option for controlling oxygen concentration in large loops including HELIOS. (C) 2008 Elsevier B.V. All rights reserved.