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Gasification of greek lignite in an indirect heat (allothermal) rotary kiln gasifier

机译:间接加热(铝热)回转窑气化炉中希腊褐煤的气化

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摘要

This work reports the performance results of a pilot-size lignite gasification plant. The feed material was Greek lignite (Megalopolis), currently being employed for electricity generation in pulverized lignite-fired thermoelectric stations. Low energy conversion efficiency, low station availability, and environmental issues call for developing improved processes, e.g., an IGCC (Integrated Gasification Combined Cycle). An indirect heat (allothermal) rotary kiln was selected as the lignite gasification reactor for developing an overall gasification process of improved efficiency. Weeklong gasification runs, at near atmospheric pressure and maximum temperature in the range 900-950 ℃, validated high DAF lignite conversions, i.e., 90-95%, and the production of a medium heating value synthesis gas (i.e., 11-13 MJ/Nm~3 dry basis), despite the use of air for burning recycled product gas for process heating. Gas composition is equivalent to that of autothermal gasifiers (e.g., Lurgi, Winkler, Koppers-Totzek), which operate on oxygen, under pressure and strict moisture and particle size specifications. Similarly, the kiln gas is comparable to that of an allothermal, high-pressure, fluidized bed gasifier running with a high rank coal feed. The data indicate satisfactory gasification efficiency and a good thermal efficiency that should be improved further through heat integration of a scaled-up process based on an indirect heat rotary kiln gasifier.
机译:这项工作报告了中试规模褐煤气化厂的性能结果。原料为希腊褐煤(Megalopolis),目前正在粉煤褐煤热电站中用于发电。能量转换效率低,电站利用率低以及环境问题要求开发改进的工艺,例如IGCC(整体气化联合循环)。选择间接加热(铝热)回转窑作为褐煤气化反应器,以开发提高效率的整体气化工艺。在接近大气压且最高温度在900-950℃的范围内进行了为期一周的气化,验证了DAF褐煤的高转化率,即90-95%,并产生了中等热值的合成气(即11-13 MJ / Nm〜3(干基)),尽管使用空气燃烧回收的产品气进行过程加热。气体组成与自动热气化炉(例如Lurgi,Winkler,Koppers-Totzek)相同,它们在氧气,压力和严格的水分和粒度规格下运行。类似地,窑炉气体可与使用高级煤进料运行的同温,高压,流化床气化炉相媲美。数据表明令人满意的气化效率和良好的热效率,应通过基于间接热旋转窑气化炉的按比例放大工艺的热集成来进一步提高气化效率。

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