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Agricultural waste conversion to activated carbon by chemical activation with phosphoric acid

机译:通过磷酸化学活化将农业废弃物转化为活性炭

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摘要

Activated carbon is widely used in various processes as an inexpensive and effective adsorbent. The adsorption properties of activated carbon vary with the feed materials used and the method of activation. The use of an inexpensive material and performing a suitable, production method may help to generate a low cost product. Agricultural wastes could be considered as suitable raw materials for the production of activated carbon. In this work, activated carbon was produced by chemical activation with phosphoric acid of agricultural wastes such as bagasse, hard shells of apricot stones, almond, walnut and hazelnut shells. The effects of various preparation variables on both yield and quality of the prepared carbon were studied. The results showed that the selection of final activation temperature, heating rate, activation time and impregnation rate of the chemical agent was important in determining the quality of activated carbon obtained. The surface area and ash content of the activated carbon produced were compared to those of imported commercial samples. According to the results obtained, activated carbon from the hard shells of apricot stones have the best adsorption properties and the highest surface area. This activated carbon could be used in the separation of metal ions from wastewaters.
机译:活性炭作为廉价且有效的吸附剂被广泛用于各种方法中。活性炭的吸附性能随所用原料和活化方法而变化。使用便宜的材料并执行合适的生产方法可能有助于产生低成本的产品。农业废物可以被认为是生产活性炭的合适原料。在这项工作中,活性炭是通过用农业废料(例如蔗渣,杏石的硬壳,杏仁,核桃和榛子壳)中的磷酸进行化学活化而生产的。研究了各种制备变量对制备碳的收率和质量的影响。结果表明,最终活化温度,加热速率,活化时间和化学试剂的浸渍速率的选择对于确定所得活性炭的质量至关重要。将生产的活性炭的表面积和灰分与进口的商业样品进行了比较。根据获得的结果,来自杏核硬壳的活性炭具有最佳的吸附性能和最大的表面积。该活性炭可用于从废水中分离金属离子。

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