Carbon encapsulated RuO2 nano-dots anchoring on graphene as an electrode for asymmetric supercapacitors with ultralong cycle life in an ionic liquid electrolyte

摘要

Assembling asymmetric y efficient strategy to enhance the energy density of SCs. However, the poor cycle stabilitysupercapacitors (SCs) combined with ionic liquid (IL) electrolytes is a ver of pseudocapacitive metal oxides in ILs seriously affects the performance of this class of asymmetric SCs. Improving the structural stability of metal oxides during the charge/discharge process is one of the greatest challenges at present. Herein, RuO2 nano-dots/reduced graphene oxide (RGO) composites are firstly prepared, and an IL-based asymmetric SC is built using the component-optimized composite (20 wt% RuO2/RGO) as the cathode and activated polyaniline-derived carbon nanorods (denoted as APDC) as the anode. It exhibits a high energy density of 108 W h kg(-1), but shows poor cycling stability. In order to solve this problem, an ultrathin carbon layer originating from glucose is employed to encapsulate RuO2 nano-dots anchoring on RGO, forming a core/shell structure of RuO2@C. With the protection of the carbon shell, the as-made RuO2@.C/RGOHAPDC asymmetric SC exhibits superior long-term stability with 98.5% capacitance retention after 100 000 cycles in the IL electrolyte, as well as a high energy density of 103 W h kg(-1) with a potential window of 3.8 V. Furthermore, this protection mechanism of the carbon layer is analyzed by electrochemical quartz crystal microbatance experiments.