TiO_2-based photocatalytic process for purification of polluted water: Bridging fundamentals to applications

摘要

Recent years have witnessed a rapid accumulation of investigations on TiO2-based photocatalysis, which poses as a greatly promising advanced oxidation technology for water purification. As the ability of this advanced oxidation process is well demonstrated in lab and pilot scales to decompose numerous recalcitrant organic compounds and microorganism as well in water, further overpass of the hurdles that stand before the real application has become increasingly important. This review focuses on the fundamentals that govern the actual water purification process, including the fabrication of engineered TiO_2-based photocatalysts, process optimization, reactor design, and economic consideration. The state of the art of photocatalyst preparation, strategies for process optimization, and reactor design determines the enhanced separation of photo-excited electron-hole (e-h) pairs on the TiO_2 surface. For the process optimization, the kinetic analysis including the rate-determining steps is in need. For large-scale application of the TiO_2-based photocatalysis, economics is vital to balance the fundamentals and the applied factors. The fundamentals in this review are addressed from the perspective of a bridge to the real applications. This review would bring valuably alternative paradigm to the scientists and engineers for their associated research and development activities with an attempt to push the TiO_2-based photocatalysis towards industrially feasible applications.