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首页> 外文期刊>Journal of Molecular Liquids >Tin oxide nanoparticle loaded on activated carbon as new adsorbent for efficient removal of malachite green-oxalate: Non-linear kinetics and isotherm study
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Tin oxide nanoparticle loaded on activated carbon as new adsorbent for efficient removal of malachite green-oxalate: Non-linear kinetics and isotherm study

机译:负载在活性炭上的氧化锡纳米颗粒作为有效吸附孔雀石绿草酸盐的新型吸附剂:非线性动力学和等温线研究

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摘要

In this work Tin oxide nanoparticles were synthesized and loaded on activated carbon (SnO_2–NP–AC). Prepared SnO_2–NP–AC was used as an adsorbent for the removal of Malachite green-oxalate from aqueous medium. The morphological properties of the prepared adsorbentwere investigated by using X-ray diffraction (XRD), scanning electron microscope (SEM) and BET analysis. The removal percentage in batchmodewas investigated at various operating parameters like; initial pH, contact time, amount of adsorbents and initial dye concentration. The experimental equilibrium data were analyzed by using various models and it was seen that Langmuir isotherm model fitted well with maximum monolayer adsorption capacity of 142.87 mg g~(?1). The adsorption kinetic data followed both pseudo second-order kinetics and intraparticle diffusion mechanism.
机译:在这项工作中,合成了氧化锡纳米颗粒并将其负载在活性炭(SnO_2–NP–AC)上。制备的SnO_2-NP-AC用作吸附剂,用于从水性介质中去除孔雀石绿草酸盐。通过X射线衍射(XRD),扫描电子显微镜(SEM)和BET分析研究了所制备吸附剂的形貌。在各种操作参数下(如)研究了批处理模式下的去除率;初始pH,接触时间,吸附剂的量和初始染料浓度。通过各种模型对实验平衡数据进行了分析,发现Langmuir等温模型拟合得很好,最大单层吸附量为142.87 mg g〜(?1)。吸附动力学数据遵循伪二级动力学和颗粒内扩散机理。

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